to chat via video 
TinyChat

The link to it is here .
VChatter

Click here .
Rounds Video Chat

You can find the application here .
FaceBuzz
FaceBuzz 
If you still want to try it out, here is the link .
ChatVibes

The link is here .
Conclusion:
From my point of view, TinyChat the best and easiest function for video chatting on Facebook. So here's a little how to.

As soon as you add the application to your profile at http://www.facebook.com/apps/application.php?id=140802830263 , it starts. The chat room opens automatically, where you can also invite your friends to video chat. If you do not remove the check mark beforehand, the application automatically posts a message to the profile.

Using the chat is very easy.
However, it is advisable to use a headset to avoid a somewhat loud echo. You can select your webcam and microphone using the menu on the right. Of course, in addition to video chatting, you can also use normal written chat. You can also use the settings icon to cast the screen and use other additional functions.
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